Cross metathesis of (-)-β-pinene, (-)-limonene and terpenoids derived from limonene with internal olefins

The straightforward functionalization of sterically demanding α,α-disubstituted double bonds β-pinene, (-)-limonene and terpenoids has been achieved via cross metathesis with internal olefins. reactions are catalyzed by second generation ruthenium catalysts in dimethyl carbonate as green solvent or under neat conditions. This transformation provides a clean process for the access to functionalized bulky cyclic terpenes where terminal bond generates trisubstituted olefin.